A Toxological Analysis of Mercury


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Exposure Due to Food Consumption

Organic mercury compounds like methyl mercury can enter the body readily through three routes - lungs, skin and stomach. The main human exposure to mercury is through ingestion of fish that contain methyl mercury. Completely cutting fish out of the diet is not advised however because there are many benefits to eating fish. Fish are an excellent source of protein and are low in saturated fat; therefore a balanced diet is necessary. In order to protect Canadians, Health Canada is advising a guideline of 0.5 parts per million of total mercury per gram of fish tissue in commercial fish. Commonly consumed marine species such as salmon, cod, pollock, sole, shrimp, mussels, scallops and canned tuna, have mercury levels that generally fall below this limit and are therefore considered safe for consumption.

 

Shark, swordfish and fresh or frozen tuna generally have concentrations ranging from 0.5 to 1.5 ppm. This occurs because methyl mercury accumulates in higher amounts up the aquatic food web meaning that larger predator fish have the highest content of methyl mercury. These fish are considered to be the exceptions to the 0.5 ppm guideline because they are considered "gourmet" fish and are not typically eaten in high enough quantities to pose a health hazard. A consumption limit of one meal per week of these fish is recommended and women of child bearing age, pregnant women, and children should not consume these fish more than once per month. Fish containing over 1.5 ppm are not considered suitable for human consumption at any time.

 

  Freshwater fish species such as pike, bass and walleye have also been know to attain elevated methyl mercury levels in various lakes and river systems. If fish constitutes a staple part of the diet, such as for indigenous peoples and recreational anglers, consumption of these species may increase risk of mercury exposure. In Canada, thousands of advisories on fish species from individual water bodies are put in place in every year due to excessive mercury contamination of fish tissues. The EPA’s 2001 National Listing of Fish & Wildlife Advisories consists of more than 2,000 advisories in the United States to help the public find sources where fish are low in toxic pollutants so they can safely enjoy the benefits of eating fish. Each advisory contains information about:

 

  • species and size of fish / wildlife covered in the advisory
  • specific chemical contaminants of concern
  • location of selected water-bodies
  • special populations at risk
  • names, phone numbers and web-sites of local contacts

 

Exposure due to inhalation


Mercury is extremely volatile in its elemental form and can give off mercury vapor at room temperature. This vapor can be inhaled into the lungs and passed into the blood stream. Based on available science, normal air concentrations of mercury vapor, averaging 1.6 nanograms per cubic meter of air, do not appear to be a cause for concern. However, inhalation can be a significant route of exposure when mercury-silver amalgam is used in dental fillings.

 

Exposure Due to Contact

Dermal contact is also a route of exposure to mercury with alkyl mercury compounds being particularly notorious. Liquid mercury may pass through the skin and into the blood stream causing it to be lethal at some doses. In 1997, a researcher named Karen Wetterhahn, from Dartmouth College in New Hampshire, died when a single drop of dimethylmercury passed through her protective latex glove and through her skin.

 

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